©
COPYRIGHT 2000 THE ESAB GROUP, INC. LESSON
V
5.4.1.2 If
the weldment is to be used in corrosive service, the carbide precipitation and
resultant intergranular corrosion must
be eliminated. Three dependable methods of controlling
this problem are defined below:
a. Carbide precipitation
is a function of the carbon content. Keeping the carbon content
as low as possible in the steel (0.04%
maximum) and welding it with low carbon elec- trodes
is one solution. b. If
the carbon of the steel and weld metal are tied up by an element that has a stronger
affinity for carbon than does chromium,
carbide precipitation cannot occur. Columbium and
titanium are alloys that have a stronger affinity for carbon. Steels with
columbium or titanium,
and covered electrodes with columbium present, are made for this purpose.
c. Another method,
although not as practical, is to heat the finished weldment to at least
1850°F allowing all of the
precipitated carbides to go back into solution. The weldment
is then rapidly cooled and quenched
so that it passes through the critical temperature (1200°F)
very quickly, allowing little or no carbides to reform. However, stainless
steel weldments
heated to such high temperatures would be subject to warping, sagging and
other loss of dimension as well as
being covered with heavy scale. 5.4.2
Ferrite
in Austenitic
Stainless Steel
- Stainless weld metal that is fully austenitic is
non-magnetic and has a relatively large
grain structure. This results in the weld being crack-
sensitive. By controlling the
balance of the alloying elements in the electrode, small amounts of
another phase, ferrite, can be introduced
in the weld metal. The ferrite phase causes the austenitic
grains to be much finer and the weld becomes more crack-resistant.
5.4.2.1 Certain
alloying elements used in stainless steels and weld metals behave as
austenite stabilizers and others as
ferrite stabilizers. Among the austenite stabilizers are
nickel, carbon, manganese and nitrogen.
The ferrite stabilizers are chromium, silicon, molyb-
denum and columbium. It is the
balance between the two types of alloying elements that controls
the quantity of ferrite in the weld metal. INSIDE
OF TANK
HEAT AFFECTED
ZONES WELD
METAL INTERGRANULAR
CORROSION FIGURE
8